Volume 7 Issue 3
5,11,17,23-Tetra-tert-butyl-25-(2’-pyridylmethylamidocarbonylmethyl)-calix[4]arene
Abdullah Sulaiman Al-Ayed, Lassaad Baklouti and Abdelwaheb Hamdi
1Chemistry Department, Faculty of Science and Arts at El-Rass, Qassim University, Kingdom of Saudi Arabia
2Laboratoire d’Application de la Chimie aux Ressources et Substances Naturelles et à l’Environnement (LACReSNE), Faculté des Sciences de Bizerte, Tunisia
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Abstract
It has recently been shown that Severe Plastic Deformation (SPD) techniques could be used to obtain nanostructured metal hydrides with enhanced hydrogen sorption properties. In this paper we review the different SPD techniques used on metal hydrides and present some specific cases of the effect of cold rolling on the hydrogen storage properties and crystal structure of various types of metal hydrides such as magnesium-based alloys and body centered cubic (BCC) alloys. Results show that generally cold rolling is as effective as ball milling to enhance hydrogen sorption kinetics. However, for some alloys such as TiV0.9Mn1.1 alloy ball milling and cold rolling have detrimental effect on hydrogen capacity. The exact mechanism responsible for the change in hydrogenation properties may not be the same for ball milling and cold rolling. Nevertheless, particle size reduction and texture seems to play a leading role in the hydrogen sorption enhancement of cold rolled metal hydrides.
Keywords:metal hydrides; severe plastic deformation; cold rolling; BCC alloys; magnesium-based alloys